Chrono-environnement - UMR 6249 CNRS/UFC
Campus de la Bouloie
16 rue de Gray
25030 Besançon cedex
France
Grégorio Crini
Senior Engineer
POLLUTION
gregorio.crini@-Code to remove to avoid SPAM-univ-fcomte.fr
+33 (0)3 81 66 57 01, room -207M (La Bouloie)
0000-0003-2540-6851 gregorio-crini
Analytical chemistry – Organic chemistry – Water chemistry – Water engineering – Environmental chemistry – Spectroscopy – Organic and macromolecular synthesis – Polymer and plastic materials – Cyclodextrins – Chitin/chitosan – Solid state NMR – Hemp – Industrial expertise – PFAS
Presentation
My research focuses on the use of bioprocesses (biocoagulation, bioflocculation, biodegradation, bioadsorption), natural substances (starches, cyclodextrins, dextrins, chitin, chitosans, celluloses, wood, hemp and flax) and organisms (insects) in the treatment of industrial water and sewage sludge.
Once developed, macromolecular constructs based on these substances are proposed for the complexation, capture, transport and separation of contaminants present in effluents (industrial, urban, aquatic) and sludge, involving both chemical abatement and environmental impact. The contaminants and pollutants mainly targeted are metals (base, precious), metalloids, other minerals (fluorides, sulfates, phosphates), organics (PAHs, PCBs, nitrogenous fungicides), emerging substances (PFAS, alkylphenols, surfactants) and global water parameters (TSS and colloids, COD, BOD, nitrogen, hydrocarbons).
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Recent Publications
Journal articles
2024
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- Grégorio Crini, Dario Lacalamita, Eric Lichtfouse, Nadia Morin-Crini, Chong Liu, et al.. Characterization and treatment of industrial laundry wastewaters: a review. Environmental Chemistry Letters, In press, ⟨10.1007/s10311-024-01770-y⟩. ⟨hal-04671093⟩
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- Dario Lacalamita, Chiara Mongioví, Grégorio Crini. Chemical oxygen demand and biochemical oxygen demand analysis of discharge waters from laundry industry: monitoring, temporal variability, and biodegradability. Frontiers in Environmental Science, 2024, 12, ⟨10.3389/fenvs.2024.1387041⟩. ⟨hal-04610559⟩
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- Chong Liu, Grégorio Crini, Lee Wilson, Paramasivan Balasubramanian, Fayong Li. Removal of contaminants present in water and wastewater by cyclodextrin-based adsorbents: A bibliometric review from 1993 to 2022. Environmental Pollution, 2024, 348, pp.123815. ⟨10.1016/j.envpol.2024.123815⟩. ⟨hal-04609323⟩
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- Chiara Mongiovi, Xavier Gabrion, Jason Govilas, Wajih Akleh, Mario Scheel, et al.. Adsorption location of copper on hemp shives revealed by combination of K-edge subtraction X-ray microtomography and X-ray micro-fluorescence. Cellulose, 2024, 31 (2), pp.809 - 822. ⟨hal-04528333⟩
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2023
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- Chloé Godeau, Nadia Morin-Crini, Grégorio Crini, Jean-Philippe Guillemin, Anne-Sophie Voisin, et al.. Field-Crop Soils in Eastern France: Coldspots of Azole-Resistant Aspergillus fumigatus. Journal of Fungi, 2023, 9 (6), pp.art. 618. ⟨10.3390/jof9060618⟩. ⟨hal-04165581⟩
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- Dario Lacalamita, Guillaume Hoyez, Chiara Mongioví, Anne Ponchel, Nadia Morin-Crini, et al.. Efficient removal of fluoride ions present in industrial effluents using metal-organic frameworks of UiO-66-NH2. Journal of Water Process Engineering, 2023, 53, pp.103791. ⟨10.1016/j.jwpe.2023.103791⟩. ⟨hal-04102244⟩
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- Dario Lacalamita, Chiara Mongioví, Grégorio Crini. Chemical substances present in discharge water generated by laundry industry: Analytical monitoring. Water Science and Engineering, 2023, 16 (4), pp.324-332. ⟨10.1016/j.wse.2023.07.004⟩. ⟨hal-04610566⟩
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- Chiara Mongioví, Xavier Gabrion, Jason Govilas, Wajih Akleh, Mario Scheel, et al.. Adsorption location of copper on hemp shives revealed by combination of K-edge subtraction X-ray micro-tomography and X-ray micro-fluorescence. Cellulose, 2023, 31 (2), pp.809 - 822. ⟨10.1007/s10570-023-05685-9⟩. ⟨hal-04663841⟩
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- Chiara Mongioví, Maélys Jaillet, Dario Lacalamita, Nadia Morin-Crini, Michael Lecourt, et al.. A Strategy to Valorize a By-Product of Pine Wood (Pinus pinaster) for Copper Removal from Aqueous Solutions. Molecules, 2023, 28 (18), pp.6436. ⟨10.3390/molecules28186436⟩. ⟨hal-04286257⟩
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- Chiara Mongioví, Grégorio Crini. Copper Recovery from Aqueous Solutions by Hemp Shives: Adsorption Studies and Modeling. Processes, 2023, 11 (1), pp.191. ⟨10.3390/pr11010191⟩. ⟨hal-04286268⟩
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- Lorenzo Picos-Corrales, Ana Morales-Burgos, Jose Ruelas-Leyva, Grégorio Crini, Evangelina García-Armenta, et al.. Chitosan as an Outstanding Polysaccharide Improving Health-Commodities of Humans and Environmental Protection. Polymers, 2023, 15 (3), pp.526. ⟨10.3390/polym15030526⟩. ⟨hal-04286282⟩
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2022
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- Grégorio Crini, Cesare Cosentino, Corina Bradu, Marc Fourmentin, Giangiacomo Torri, et al.. Innovative technologies to remove alkylphenols from wastewater: a review. Environmental Chemistry Letters, 2022, 20, pp.2597-2628. ⟨10.1007/s10311-022-01438-5⟩. ⟨hal-03669982⟩
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- Grégorio Crini, Corina Bradu, Marc Fourmentin, Cesare Cosentino, Ana Rita Lado Ribeiro, et al.. Sorption of 4-n-nonylphenol, 4-n-octylphenol, and 4-tert-octyphenol on cyclodextrin polymers. Environmental Science and Pollution Research, 2022, 29 (1), pp.171-181. ⟨10.1007/s11356-021-14435-y⟩. ⟨hal-03324572⟩
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- Eric Lichtfouse, Nadia Morin-Crini, Corina Bradu, Youssef-Amine Boussouga, Mehran Aliaskari, et al.. Methods for selenium removal from contaminated waters: a review. Environmental Chemistry Letters, 2022, 20, pp.2019-2041. ⟨10.1007/s10311-022-01419-8⟩. ⟨hal-03626838⟩
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- Chiara Mongioví, Dario Lacalamita, Nadia Morin-Crini, Xavier Gabrion, Vincent Placet, et al.. Use of chènevotte, a valuable co-product of industrial hemp fiber, as adsorbent for copper ions: Kinetic studies and modeling. Arabian Journal of Chemistry, 2022, Arabian Journal of Chemistry, 15 (4), pp.103742. ⟨10.1016/j.arabjc.2022.103742⟩. ⟨hal-04055671⟩
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- Chiara Mongioví, Grégorio Crini, Xavier Gabrion, Vincent Placet, Virginie Blondeau-Patissier, et al.. Revealing the adsorption mechanism of copper on hemp-based materials through EDX, nano-CT, XPS, FTIR, Raman, and XANES characterization techniques. Chemical Engineering Journal Advances, 2022, 10, pp.100282. ⟨10.1016/j.ceja.2022.100282⟩. ⟨hal-04664259⟩
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- Chiara Mongiovi, Grégorio Crini, Xavier Gabrion, Vincent Placet, Virginie Blondeau-Patissier, et al.. Revealing the adsorption mechanism of copper on hemp-based materials through EDX, nano-CT, XPS, FTIR, Raman, and XANES characterization techniques. Chemical Engineering Journal Advances, 2022, 10, pp.100282 (12). ⟨10.1016/j.ceja.2022.100282⟩. ⟨hal-03813238⟩
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- Nadia Morin-Crini, Eric Lichtfouse, Guorui Liu, Vysetti Balaram, Ana Rita Lado Ribeiro, et al.. Worldwide cases of water pollution by emerging contaminants: a review. Environmental Chemistry Letters, 2022, 20, pp.2311-2338. ⟨10.1007/s10311-022-01447-4⟩. ⟨hal-03662990⟩
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- Nadia Morin-Crini, Eric Lichtfouse, Marc Fourmentin, Ana Rita Lado Ribeiro, Constantinos Noutsopoulos, et al.. Removal of emerging contaminants from wastewater using advanced treatments. A review. Environmental Chemistry Letters, 2022, 20, pp.1333-1375. ⟨10.1007/s10311-021-01379-5⟩. ⟨hal-03523724⟩
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- María Isabel Rodríguez-López, José Antonio Pellicer, Teresa Gómez-Morte, David Auñón, Vicente Gómez-López, et al.. Removal of an Azo Dye from Wastewater through the Use of Two Technologies: Magnetic Cyclodextrin Polymers and Pulsed Light. International Journal of Molecular Sciences, 2022, 23 (15), pp.8406. ⟨10.3390/ijms23158406⟩. ⟨hal-04286288⟩
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- Giangiacomo Torri, Annamaria Naggi, Eric Lichtfouse, Grégorio Crini. Professor Casu’s contribution to cyclodextrins, the remarkable cage-shaped molecules: a review. Environmental Chemistry Letters, 2022, 20, pp.2085-2095. ⟨10.1007/s10311-022-01417-w⟩. ⟨hal-03662809⟩
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Book sections
2024
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- D. Lacalamita, S. Bertini, C. Mongioví, C. Cosentino, N. Morin-Crini, et al.. Characterization of Cyclodextrin Cross-linked Polymers Used in Environmental Applications by Solid-state NMR Spectroscopy: a Historical Review. Pellegrino, Conte; Delia, Francesca; Chillura, Martino; Paolo Lo, Meo. The Environment in a Magnet : Applications of NMR Techniques to Environmental Problems (Issn), Royal Society of Chemistry, pp.316-352, 2024, 978-1839167348. ⟨10.1039/BK9781837671250-00316⟩. ⟨hal-04555193⟩
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2022
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- Chiara Mongiovi, Nadia Morin-Crini, Vincent Placet, Corina Bradu, Ana Ritta Lado Ribeiro, et al.. Cannabis/Hemp for Sustainable Agriculture and Materials. Hemp-based materials for applications in wastewater treatment by biosorption-oriented processes : A review, pp.239 - 295, 2022. ⟨hal-03818662⟩
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- Chiara Mongioví, Nadia Morin-Crini, Vincent Placet, Corina Bradu, Ana Rita Lado Ribeiro, et al.. Hemp-Based Materials for Applications in Wastewater Treatment by Biosorption-Oriented Processes: A Review. Cannabis/Hemp for Sustainable Agriculture and Materials, Springer Singapore, pp.239-295, 2022, ⟨10.1007/978-981-16-8778-5_9⟩. ⟨hal-04286375⟩
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Books
2022
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- Grégorio Crini. 2.Chitin and Chitosan. Discoveries and Applications for Sustainability. Elsevier. 2022, ⟨10.1007/978-0-323-96119-6⟩. ⟨hal-04610818⟩
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